Long before Anna Gunn played the worrisome wife of Walter White on âBreaking Bad,â she had a career in theater, television, film and even as a voice actress. She rose to fame playing the jealous and perplexed Martha Bullock on HBOâs âDeadwoodâ (2005). Before that, Gunn made television appearances on âSeinfeldâ (1993), âERâ (1999) and âSix Feet Underâ (2004). The New Mexico native also starred in films alongside Angelina Jolie in âWithout Evidenceâ (1995) and beside Jon Voight in âEnemy of the Stateâ (1998). Her voice can be heard in the âLegacy of Kainâ video game series as the character Ariel. Sheâs pictured above left in the 1996 Taper play âHysteria.â (Carol Cheetham / Los Angeles Times / AMC)